Silver Solder

The most important thing for good soldering is keeping the iron tip clean. It is good to develop a habit of wiping the tip on a wet sponge whenever you pick up the iron.

With the HASL or ENIG finish that we are most likely to see in PCBs, the Kester Sn63/Pb37 rosin core is pretty much the best there is. It flows well and doesn't need as high a temperature as other alloys.
 
Wondering if there is any evidence that Silver solder, or other alloys, have beneficial results?
Hello, Good soldering practices are far more important to good connections than adding a small amount of silver to the mix:

1. What you want soldered having a good electrical connection, no gaps between the wire and the connector. Solder is not gap filling glue.
2. Making sure both sides are clean.
3. Using the proper temperature iron, helps quite a bit to get good flow, without harming anything like PCB traces.
4. Checking after you solder to see if the flow was smooth and even.

And for good looks mostly, using some alcohol to clean off the resin residue when done.

Pretty basic stuff, but works to get good connections.

( I have had both Military and NASA specification soldering classes and been soldering for over 65 years now, so believe I am qualified to comment on this. )

Regards,
Greg
 

Cardas Quad Eutectic has the same four elements that the Fire-metall does. And Cardas are equally cagey about the percentages of silver and copper added.

I'm always wary when a manufacturer of solder does not tell you the precise composition - all regular solder manufacturers, whether lead-free or tin/lead formulations tell you precisely what is in there including any impurities.
 
As sawyers indicated, the percentages matter; they can very wildly.

Here 'silver solder' has high percentage of silver, typically around/above 50% for instance. It is what I use (with special fluxes) to braze stainless steel components together (using high temperature blow torches etc).

The stuff used in electronics would usually have 'much' less silver, maybe just a few percent, and so melts with a small soldering iron. In my area of the world it would more correctly be called 'silver-bearing' solder since the silver is a relatively minor component. But the amount of silver it contains is open to huge variation, so if not specified (and by a manufacturer you trust) then treat with caution when pricing it.

FWIW I think the use-cases for silver-bearing solder are limited; some people assume it must be better because it costs more, but IMO it isn't needed or even particularly beneficial as a general electronic solder for PCBs etc.
 
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I'm surprised one of if not the most important points has not been mentioned. Use flux. I've taken the Pace high reliability solder course as well as one of our local colleges excellent SMD solder course and both stressed the importance of fluxing the joint.In addition,clean the leads of components,pads of circuit boards with 99% isopropyl alcohol and lint free wipes. Do not use rubber erasers, non lint free wipes etc. as they leave residue.
 
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Wondering if there is any evidence that Silver solder, or other alloys, have beneficial results?
Well of course!
Forget snake oil and mojo, advantages are serious and real.

From chemical/metallurgical points:

Tin-silver-copper (Sn-Ag-Cu, also known as SAC), is a lead-free (Pb-free) alloy commonly used for electronic solder. It is the main choice for lead-free surface-mount technology (SMT) assembly in the industry,[1] as it is near eutectic, with adequate thermal fatigue properties, strength, and wettability
 
Wondering if there is any evidence that Silver solder, or other alloys, have beneficial results?

In my experience (for people with hobby-grade tools and hobby-grade soldering technic) silver-bearing solder creates more problems than it solves.

The biggest issue is that most of the time it comes in lead-free variants, which is significantly more difficult to work with and super easy to create dirty or cold joints.

The amount of ridiculously botched modifications I have seen in high-end audio equipment is ridiculous. Yet people keep asking for it and people keep obliging

The good old 60-40 is often guilty for the same reason. It stays liquid for longer and can be moved around probably more than it should

0.5mm 63/37 is probably the best choice for 99.99999% of hobbyists and cases