Microcontroller - Decoupling caps/bypass

Hello everyone,
I'm looking to add some bypass/decoupling capacitor on a microcontroller unit but I was thinking which rail would be the best to bypass/decouple.
I've got some options like VDD-VDDA-VSSA etc etc, i'm not an expert in this just an hobbyist.
Thanks!

microcontroller.png
 
Your first post is not clear to me: what do you mean by 'microcontroller unit '?
Is this a ready made board with microcontroller such as an Arduino or similar?
Or are you building your own board with a microcontroller ic?
If the first then it should be sufficient to decouple the main supply.
If the latter then you need the datasheet.