toroidal transformer rewind

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...........I am curious if the PVC insulated wire will be ok 😉
NO !!!!
enamelled copper wire comes in various temperature grades from ~130°C to over 200°C

PVC insulated wire is probably rated for <100°C

A follow up to earlier.
Doubling the output voltage will require a lot of copper. I doubt there will be room to add enough turns to get near your target.
 
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