CCS values

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The TL431 datasheet cautions you to (a) never apply more than 36 volts across it; (b) run it at a cathode bias current greater than 1mA and less than 100mA. In your circuit this means you want VI(BATT) less than 36 volts, and you want
  • R > VI(BATT) / 0.1A
  • R < [ VI(BATT) - 2.5 ] / 0.001A
If you can't connect the resistor straight to your positive power supply, because your power supply voltage is more than 36 volts, then what? You can always build a resistive voltage divider to create a node voltage that's below 36V, and use that node voltage to bias your TL431. Another way to skin the cat is to build a 20V shunt regulator using a resistor and a zener, then bias your TL431 from the 20V point.
 
No more than 50V with a BC550.As long as the transistor is ok the TL431 sees no more then the Vref (2V5) + Vbe (~0V6), not to worry.
The resistors are as the picture shows, giving the TL431 a 1m5A bias to be on the safe side of the minimum 1mA of the datasheet.
Mona
 

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