Bipolar electrolytics vs back to back standard

As noted in various posts, an aluminium electro is a diode with a knee around 1.5V, so if operating about 1V or so there is no reason for them to ever be 'formed'.

The problem with back-to-back (seperate or integrated (bipolar) is that for 2 x 1V = 2V of signal neither is a diode so you get the series capacitance: i.e. two 22uF gives you 11uF.

But above 1.5V in any direction one becomes a diode, so you suddenly get 22uF, with a diode. I.e the capacitance varies non-linearly with the voltages we are most likely to listen to.

So for any audio work I would suggest you bypass them as much as possible with film, and think about stacking them so they never hit that 'knee' of the diode.

Recently as a feedback capacitor driven at 1k/33k = 1/33 of the output voltage of max 50V, I decided that the max voltage of 50/33 = 1.5V was better handled by replacing the 47uF (non-polar) cap with two 100uF in series (not back-to-back) and a 820n bypass (which I had spare).

Perhaps do a spice simulation or measure the max voltage across the cap in usage, and see how many volts it actually sees, and then decide how to avoid that diode 'knee', as I don't think it's an aid to audio quality 😀
 
In an active circuit you can bias the mid-point of back-to-back electrolytics to the appropriate rail with 1M+ resistor, putting both caps into a more linear part of their curve, though adding a small amount of leakage current of course.
Like this in fact:
electrolytics-back-to-back-sch.JPG


(resistor is 1M)

I measured this with bias, no bias, floating and with the electrolytics in series rather than back-to-back:
electrolytics-back-to-back.png



So the biasing has a small effect (this is steady state, transients presumably are greatly helped). The test was at 250Hz, leading to 5dB attenuation so upto about 5V across the caps, 10% of their voltage rating.

0.0004% isn't bad around the 6dBV level (2Vrms) all things considered....

Here's some more detail on the harmonics, showing predominantly 3rd:

electrolytics-back-to-back-harms2.png

electrolytics-back-to-back-harms.png
 
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