best caps for audio

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Each cap needs to be chosen for its particular role in the circuit, as SY said. By 'chosen' I primarily mean technology (e.g. dielectric), not brand. The circuit designer may have a view on this - after all, he should know exactly what each cap is doing.

As a general rule, decoupling caps should be physically small so they don't have too much inductance. A decoupler operating on its own may need lowish ESR (e.g. plastic film) while one paralleling a larger one may need higher ESR (e.g. high-K ceramic).

Coupling or feedback caps setting bandwidth need to be linear. For others it may be less important. Physically big caps may pick up more noise and interference, or create unwanted capacitive feedback leading to instability.
 
Does the input cap set the LF rolloff? If so, you want a linear dielectric so best to avoid polyester/mylar. If not, almost any film cap will do. In either case, avoid physically large caps as these can pick up hum/noise.

As I hope you are beginning to realise, there is no such thing as 'best' cap even given the circuit position because position does not contain the full story.
 
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