Do hard coat anodized aluminum heat sinks require non conductive grease or pad between chip and heatsink

I've read that a hard coated anodized aluminum surface results in a non-ferrous layer that can resist up to 120V. If that is true, why use grease or pads between a chip and heatsink surface?
 
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Well, yes the anodizied layer on aluminum is an insualtor, but it is not relied upon when electrical insulation is required. It is very thin and can be damaged during assembly. Pads, along with the right mounting hardware will provide both electrical insulation and thermal conductivity improvement.
 
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Just because I'm curious: Where do you have hard anodized radiators from?

Pretty much everything we are having to do with is anodized for decorative purposes and dyed and this is a process resulting in a rather thin oxide layer.
Hard anodizing produces a pretty thick oxide layer that is also very tough. Just like other DIYers pointed out already, I would not trust the oxide layer for insulation although it may work.

According to my experience, hard anodized surfaces come in a variety of random colors from shades of gray over gold to brown. Every batch I received had a different color. Different aluminum alloys also contribute to the color. This is why hard anodizing is not used for parts where appearance matters.
 
In principle, anodization is not designed to serve as an isolation in items not specifically intended for that purpose, thus you should refrain...
But, I did make a try on a particularly robust example, knowing that it might turn sour:
https://www.diyaudio.com/community/threads/chip-amp-photo-gallery.79303/post-4003957
It didn't, and this piece of gear is still working spotlessly, but your mileage may vary: I made sure that the dielectric strength of this heatsink was high enough, with a lot of safety margin.
Mechanically, the layer was (and is) extremely resistant, but I have seen other examples where it was not the case.
Anyway, if you attempt to use it as an isolator, you should not compound possible problems by applying a conductive grease
 
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I've read that a hard coated anodized aluminum surface results in a non-ferrous layer that can resist up to 120V. If that is true, why use grease or pads between a chip and heatsink surface?

OK, it really depends on what transistors you are using.

Some transistors have a metal backplate. The metal plate is usually the collector as well. In this case, you cannot mount the trasistor onto the heatsink without any insultation, it will cause short-circuit. You need to use insulation pads. Most insulation pads double up as thermal pads as well, so you do not need any thermal grease.

However, there are transistors which has a plastic/resin back instead of metal. They do not need insulation pads. You should apply thermal grease to improve thermal conductivity.

Btw, there are a small handful of thermal grease which are electrical conductive (most are not). They are mostly carbon/metal ones. Below is an example. I don't think it is recommended to them.

https://www.thermal-grizzly.com/produkte/25-conductonaut

An example of electrical and thermal conductive grease.

https://www.chemtronics.com/circuitworks-silver-conductive-grease
 
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There are a small number of grease thats both electrically and thermally conductive.
Yes, this is true and I have used them before. Not for heatsinks, but to lubricate bearings on moving metal parts and simultaneously provide a path to ground for static discharge. The petroleum based grease normally used in bearings is a quite a good insulator which allowed statc to accumulate and become a problem in our device. Silver based conductive grease worked great, and although it was expensive as greases go, it was simpler and more effective than many other static control methods we tried.
 
Do not trust the oxide layer for electrical insulation. Always treat it as a conductive surface.
If there is issue with the insulation of the oxide, will you replace another heatsink or add an insulating washer?
You will add a insulating washer of course. So just add it in the first place and forget about the 120 volts dielectric strength.
You can avoid the washer only if the heatsink could be allowed to float. (not connected to anything electrically)
Ungrounded metal parts in a system is a cause of signal radiation and dangerous at times.
Regards.
 
Some amplifier designs have all the collectors grounded - therefore no insulator and a grounded heat sink. Yet still others run the heat sink at Vcc - with a warning sticker about the exposed high voltage. Separate heat sinks for each rail of course. And some run the heat sink at speaker out (with all the collectors directly connected). Any of these avoid the need for micas/sil pads, but the most common and straightforward output stage (EF with all the transistors on one heat sink) is impossible. And none of them will assume that the anodization layer is enough. If some secondary component like the Vbe multiplier, temp sensor, or rail switch is fixed to that heat sink it has an insulator.