Linkwitz Riley is just one of many types of active crossover. Although the 4th order is by far the one that is used most frequently, there is theoretically no restriction when it comes to filter order apart form the fact that they can only be done in even number orders. But you may run into problems of component accuracy when it comes to analog implementations of high orders.
But the crossover type has nothing to do with my remark regading the quality of the capacitors used. Usually, SMD caps can't be had as high quality foil caps.
Regarding a pre-made crossover board: You can't just use a given board like that and use your favourite set of drivers, because the properties of the drivers have to be considered as well for the crossover design.
I can't remember who, but some British member of this forum once made a PCB layout for an active crossover that includes some EQ sections as well to make it more flexible.
Regards
Charles