Bipolar capacitors for decoupling?

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bipolar won't have "negative" pin - no front/back

no, in reverse the polar type only block ~1V so the rating of the pair would only be 35 VDC

in series you can add the V rating - if you provide some way to balance the V across the pair


if you do mean bipolar, full thickness oxide grown on both foils then you still need some V balancing technique to use at higher than individual cap rating
 
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