Not only
at the XO frequency, a larger picture should be taken into acount. The XO circuits and drivers are interacting full band. An ideal method is to flatten the impedance of the drivers first, then do the XO jobs. You'll need Zobels for the rising towards the high, LCR notch for the low end resonance... etc. Sometimes more (unfortunately).
In the end, electrical curve shape doesn't matter at all. What you should aim for is the acoustic results. It's just too complex to describe in one or two posts. Issues in drivers themselves, baffles (or boxes), the interactions between them... all over the place.
Doing XO design from scratch and by pen/paper/calculator/ears, you'll need a LOT of time. I'd suggest getting a tool to measure the impedance of the driver, and a mic+RTA to see what really happens in acoustics. Those are cheap and easy to get now. You'll be easier and much more successful with them.
Good luck
