If you want to test them before hooking up drivers and to an amplifier to ensure you have wired them correctly (so you don't short and blow your amplifier), then connect your drivers to your crossover and use a multimeter to measure the DC resistance. If > 3 Ohms you'll be ok.
You can't really measure crossover performance without the drivers intended attached. A crude way would be to put a resistor in place of each driver rated at the drivers nominal impedance. ie. if you have an 8 ohm nominal woofer and 8 ohm nominal tweeter, put an 8 ohm resistor in place of the woofer and another in place of the tweeter.
If you are measuring the transfer function, it depends on the software you are using.
Depends on what you are trying to achieve.
Cheers,
David.