Baffle Diffraction

I am currently working on speaker build. Midrange will have enclosure behind it. This is the baffle.Tweeter will be mounted in waveguide on open baffle.I was planning to do round over but as its single 3/4 baltic ply i don't i can do large radius. I was thinking of gluing large quarter round trim instead.Would that work well?
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I do want to do round over just trying to figure out how to do it with this baffle.
Unless you can follow the waveguide design enough to extend it, you won't be sure that the flat baffle part is even optimum let alone rounding it over. Therefore you may as well determine what frequencies are reaching the edges, and provide a large enough roundover to have some effect. There's little point using a roundover if the waveguide is obscuring the cabinet edge for the frequencies where it's effective.
 
3/4" round over is common in most lumberyards. You can glue it onto the 3/4" plywood. 3/4" roundover isn't audible except to people with super hearing, it's used for aesthetics. It's almost impossible for an average person to machine hard wood into large radius 4-6" 1/4 round where it would actually affect the sound. So what to do? I've been using felt for years. As Norman points out felt can damp diffraction to good effect.

If you have access to a CNC you could machine large radius corners from whatever material you have. You could fabricate large radius corners from PVC pipe. I put sono tube baffles on my speakers as an experiment and that worked well, yes they were ugly as sin.

I'm a woodworker and can easily fabricate large curves from pine or poplar in a weekend with hand tools, this takes some experience.